A study of thallous tetracarbonyl cobaltate (-1) in solvents of varying dielectric constant by x-ray diffraction

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dc.contributor.advisor Lawrence, Richard M., 1932- en_US
dc.contributor.author Kane, Peter F. en_US
dc.date.accessioned 2011-06-03T19:31:29Z
dc.date.available 2011-06-03T19:31:29Z
dc.date.created 1975 en_US
dc.date.issued 1975
dc.identifier LD2489.Z78 1975 .K36 en_US
dc.identifier.uri http://cardinalscholar.bsu.edu/handle/handle/181092
dc.description.abstract The techniques of x-ray diffraction of liquids are employed to study the salt TlCo(CO)4 in two solvents, tetrahydrofuran and dimethylsulfoxide. Radial distribution functions calculated from scattering data are analyzed in terms of the structure of these solutions, and the results are compared to those of other studies of the same and similar solutions investigated by infrared techniques. In tetrahydrofuran, a solvent of low dielectric constant, the evidence indicates close association of anion and cation, and contact ion pair and covalent models are presented and discussed. In dimethylsulfoxide, a solvent of high dielectric constant, the evidence indicates relatively loose association or no association of anion and cation, and solvent-separated ion pair and free ion models are presented and discussed.
dc.format.extent v, 88 leaves : ill. ; 28 cm. en_US
dc.source Virtual Press en_US
dc.subject.lcsh X-rays -- Diffraction. en_US
dc.subject.lcsh Dielectrics. en_US
dc.subject.lcsh Thallous tetracurbonylcobaltate. en_US
dc.title A study of thallous tetracarbonyl cobaltate (-1) in solvents of varying dielectric constant by x-ray diffraction en_US
dc.description.notes Tables.
dc.description.degree Thesis (M.S.)
dc.identifier.cardcat-url http://liblink.bsu.edu/catkey/416081 en_US


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  • Master's Theses [5318]
    Master's theses submitted to the Graduate School by Ball State University master's degree candidates in partial fulfillment of degree requirements.

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