Optical and luminescence properties of erbium, ytterbium and terbium doped in aluminum nitride

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Authors
Corn, Tyler R.
Advisor
Maqbool, Muhammad
Issue Date
2010-07-24
Keyword
Degree
Thesis (M.S.)
Department
Department of Physics and Astronomy
Other Identifiers
Abstract

Studies have been done to determine rare-earth elements’ optical and luminescent properties using wide bandgap nitride semiconductors as suitable hosts. Research done here will contribute to the information needed to further study rare-earth elements and their unique properties. Thin films of rare-earth elements erbium, terbium, ytterbium, and both erbium and ytterbium doped into AlN are studied by laser excitation. A 532 nm Nd: YAG green laser and 783nm crystal infrared laser are used for excitation in conjunction with a spectrometer to measure photoluminescence. With the 532 nm laser, AlN: Er emits peaks at 554 nm, 561 nm, and 1552 nm, AlN: Tb emits peaks at 549 nm and 562 nm, AlN: Yb emits peaks at 966 nm, and co-doped AlN: ErYb contains peaks including both AlN: Er and AlN: Yb. Energy transfer occurred from Er to Yb resulting in an increased magnitude and peak shift. The 783 nm laser gave peaks at 1563nm for AlN: Er, 1508 nm and 1533 nm for AlN: Tb, and 1567nm for AlN: ErYb. No detectable peaks were given for AlN: Yb. A peak shift was detected in comparison of AlN: Er and AlN: ErYb. A magnetic field of 1000 G was applied to AlN: ErYb resulting in an increase in intensity of the major peak at 561nm with a splitting, creating a secondary peak at 564.5 nm. Biomedical applications can be used from the high penetration ability of lower wavelength lasers and the use of a magnetic field, which is not harmful to the human body. Enhanced green emission in erbium can be useful in future optical, photonic, and electrical devices.

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