The preparation and reactivity of group 5 indenyl complexes

dc.contributor.advisorMorris, Robert J. (Robert Joseph), 1963-2016en_US
dc.contributor.authorJefferis, Jesse M.en_US
dc.date.accessioned2011-06-03T19:36:59Z
dc.date.available2011-06-03T19:36:59Z
dc.date.created1995en_US
dc.date.issued1995
dc.description.abstractThe preparation of tri-n-butylstannylindene, has led to new synthetic routes to obtaining indenyl metal complexes of the Group V metal halides. Also, the fluxional behavior of tri-n-butylstannylindene has been studied by variable temperature 1H NMR spectroscopy.The interaction of the Group V metal halides with tri-n-butylstannylindene has led to the isolation and characterization of [(q5-C9H7)2TaC12] [TaC16] and [('q5-C9H7)2NbC12] [NbCl6]. Subsequent Lewis base chemistry has produced (T15-C9H7)TaC14(PMe3). The crystal structures of [(r15-C9H7)2TaCl2] [TaC16] and (15-C9H7)TaC14(PMe3) have been determined. The preparation and characterization of these compounds are discussed as well as the exploratory indenyl, Lewis base, and /or salt chemistry of vanadium, niobium, and tantalum.
dc.description.degreeThesis (M.S.)
dc.description.sponsorshipDepartment of Chemistry
dc.format.extentxv, 106 leaves : ill. ; 28 cm.en_US
dc.identifierLD2489.Z78 1995 .J4en_US
dc.identifier.cardcat-urlhttp://liblink.bsu.edu/catkey/958792en_US
dc.identifier.urihttp://cardinalscholar.bsu.edu/handle/20.500.14291/185203
dc.sourceVirtual Pressen_US
dc.subject.lcshMetal halides -- Synthesis.en_US
dc.subject.lcshMetal halides -- Reactivity.en_US
dc.titleThe preparation and reactivity of group 5 indenyl complexesen_US
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