The synthesis and study of phosphine functionalized crown ethers with fluorine in positions to assist with ion binding : an honors thesis (HONRS 499)
| dc.contributor.advisor | Storhoff, Bruce N. | en_US |
| dc.contributor.author | Murcia, Michael J. | en_US |
| dc.date.accessioned | 2011-06-06T19:14:23Z | |
| dc.date.available | 2011-06-06T19:14:23Z | |
| dc.date.created | 2001 | en_US |
| dc.date.issued | 2001 | |
| dc.description.abstract | Phosphine-crown ethers based on 1,3-xylyl-l8-crown-5 units with fluorine atoms in the 2-positions and P(III) donors in the 5-positions have been synthesized and characterized. The starting materials for the crown ether portions of the molecules were 4-bromo-2,6-dimethylaniline, NaBF4, NBS and tetraethylene glycol. The P(III) moieties have been introduced by generating the carbanions at the 5-positions by way of Br-Li exchange reactions. The procedures used during the synthesis along with the spectroscopic characteristics of the intermediates and final products will be discussed. | |
| dc.description.degree | Thesis (B.S.) | |
| dc.description.sponsorship | Honors College | |
| dc.format.extent | 29 leaves : ill. (some col.) ; 29 cm. | en_US |
| dc.identifier.cardcat-url | http://liblink.bsu.edu/catkey/1241927 | en_US |
| dc.identifier.other | A-247 | en_US |
| dc.identifier.uri | http://cardinalscholar.bsu.edu/handle/20.500.14291/191796 | |
| dc.source | Virtual Press | en_US |
| dc.subject.lcsh | Chemistry. | en_US |
| dc.title | The synthesis and study of phosphine functionalized crown ethers with fluorine in positions to assist with ion binding : an honors thesis (HONRS 499) | en_US |
| dc.type | Undergraduate senior honors thesis. |
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